6623-25-2

Usage

Molecular structure

complex

Functional groups

Carboxymethylsulfanyl group
4-nitrophenylmethyl group
Central sulfanylacetic acid moiety

Acidic behavior

likely due to carboxylic acid and sulfhydryl functional groups

Reactivity

potential reactivity with nucleophiles

Redox reactions

ability to undergo reduction reactions

Potential

diverse range of chemical reactions and possible biological activities

Upstream product

• 555-16-8 4-nitrobenzaldehdye 
• 68-11-1 mercaptoacetic acid 

Downstream Products

• 153258-88-9 [Methoxycarbonylmethylsulfanyl-(4-nitro-phenyl)-methylsulfanyl]-acetic acid methyl ester 
• 1410901-89-1 C₁₃H₁₅N₉O₂S₄ 
• 153258-96-9 [Ethoxycarbonylmethylsulfanyl-(4-nitro-phenyl)-methylsulfanyl]-acetic acid ethyl ester 

Relevant academic research and scientific papers

Solvent-free mechanochemical synthesis of bisthioglycolic acid derivatives: an efficient and versatile strategy for carbon–sulfur bond formation

An eco-friendly, easily achievable and efficient strategy has been explored to synthesize functionalized bisthioglycolic acids using a variety of aldehydes and thioglycolic acid. The employed protocol is solvent free and provides the desirable products in

Syntheses of some novel and symmetrical bis(4-amino-4H-1,2,4-triazole-3- thiols)

A series of bis(4-amino-4H-1,2,4-triazole-3-thiols) 3a-e were prepared by condensation reactions of 2,2-(phenylmethylene)bis(sulfanediyl)diacetic acids 2a-e with thiocarbohydrazide. The starting diacid 2a-e was prepared by reactions of aromatic aldehydes

Mass spectral studies on some nitrobenzylidene thioacetal derivatives

The electron impact mass spectral studies on some nitrobenzylidene thioacetal derivatives showed two different mechanisms of oxygen transfer from the nitro group to the sulfur containing fragments via intra-and inter-oxygen transfer. The two mechanisms ar

SYNTHESIS, SPECTRAL STUDIES AND C-S BOND FISSION THROUGH PUMMERER REACTION OF SOME ALKYLDIACETATES

A series of methyl and ethyldiacetates have been synthesized and their structures were identified.Correlation between δ-values of the benzylidene protons and ?-Hammett values has been found.The internal chemical shift Δν of the methylene protons was found to be correlated linearly with ?-Hammett constants indicating that the sulfur atom could transmit a polar effect to the substituent.Studies of H2O2 oxidation suggested that a competition between Pummerer and elimination reactions of the intermediate was involved. Key words: Benzylidene dithio diacetates; (1)HNMR spectra; Pummerer reaction