66241-48-3Relevant academic research and scientific papers
Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
Lei, Chuanhu,Yip, Yong Jie,Zhou, Jianrong Steve
supporting information, p. 6086 - 6089 (2017/05/08)
Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.
Striking Contrast between Photoinduced and Non-photoinduced Electron-transfer Reactions of 1,4-Diphenyl-2,3-diazabicyclooct-2-ene
Ikeda, Hiroshi,Minegishi, Tomonori,Miyashi, Tsutomu
, p. 297 - 298 (2007/10/02)
Photoinduced electron-transfer (PET) reactions of 1,4-diphenyl-2,3-diazabicyclooct-2-ene 1 result in a quantitative formation of 2,5-diphenylhexa-1,5-diene 2, in sharp contrast to the results of non-PET reactions and showing the importance of a back electron-transfer (BET) process in PET reactions.
Model Substances for Electro-optical and Dielectric Studies, Part I. Synthesis and Structure of 1,4-Bis(4'-dimethylamino-3',5'-dicyanophenyl)bicyclooctane
Detzer, Norbert,Burkhard, Oswald,Schaffrin, Heinz,Liptay, Wolfgang
, p. 1129 - 1141 (2007/10/02)
A synthesis for a new 1,2,6-donor-acceptor-substituted chromophoric benzene system is given.This chromophore is incorporated in a bicyclooctane system to build up model compounds for electro-optical and dielectrical studies.Furthermore a preparative convenient route to derivatives of 1,4-bis(diphenyl)bicyclooctane is worked out.The structures of the new compounds are proven by spectroscopical means. - Key words: 1,2,6-Donor-Acceptor-Substituted Benzenes, 1,4-Bis(diphenyl)bicyclooctane Derivatives
SYNTHESIS OF 1,4-DISUBSTITUTED BICYCLOOCTANES BY THE DIELS-ALDER REACTION
Geivandov, R.Kh.,Kovshev, E.I.
, p. 461 - 470 (2007/10/02)
Methods were developed for the synthesis of 1,4-diethoxy-, 1,4-dicyano-, and 1,4-diphenyl-1,3-cyclohexadienes.Their adducts with maleic anhydride, acrylonitrile, acrolein, nitroethylene, fumaronitrile, and α-acetoacrylonitrile were converted into the corresponding substituted bicyclooctanes.The configuration of the diene synthesis products was studied by IR and PMR spectroscopy.
