66270-66-4Relevant academic research and scientific papers
TRIETHYLBORANE-INDUCED RADICAL ADDITION OF ALKYL IODIDES TO ACETYLENES
Ichinose, Yoshifumi,Matsunaga, Shin-ichiro,Fugami,Keigo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3155 - 3158 (2007/10/02)
Treatment of terminal acetylenes (R1CCH) with secondary or tertiary alkyl iodides (R2I) in the presence of triethylborane provides the corresponding alkenyl iodides (R1C(I)=CHR2) in good yields.
(E)- and (Z)-(1-Iodo-1-alkenyl)silanes. Their Preparation and Their Conversion ino (E)- and (Z)-(1-Lithio-1-alkenyl)silanes
Zweifel, George,Murray, Rex E.,On, Harry P.
, p. 1292 - 1295 (2007/10/02)
(Z)-(1-Iodo-1-alkenyl)trimethylsilanes can be conveniently obtained by isomerization of the readily available E isomers through the intermediacy of (1-lithioalkenyl)silanes formed by addition of catalytic amounts of tert-butyllithium.Reaction of (E)- and
