66364-96-3

Basic information

• Product Name: C₁₃H₁₄O₅
• CAS NO: 66364-96-3
• Molecular Weight: 250.251
• Mol File: 66364-96-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₄O₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₄O₅(66364-96-3)
• EPA Substance Registry System: C₁₃H₁₄O₅(66364-96-3)

Safety Data

• Hazardous Substances Data: 66364-96-3(Hazardous Substances Data)

Upstream product

• 541-41-3 chloroformic acid ethyl ester 
• 25957-43-1 Sodium; (2R,3R)-3-methyl-3-phenyl-oxirane-2-carboxylate 

Relevant articles and documents

SYNTHESIS OF α,β-EPOXY DIAZOMETHYL KETONES

The preparation of eighteen epoxy diazomethyl ketones 1 is described.Two general methods were developed.Firstly, treatment of the mixed anhydrides of glycidic acids and carbonic acid ester with diazomethane led to the title compounds in yields ranging from 17-74 percent.Secondly, glycidyl chlorides which were obtained from sodium glycidates and oxalyl chloride, gave the desired products upon treatment with diazomethane ( yields 60-74 percent).The required α,β-epoxy carboxylic esters were prepared by Darzens condensation and epoxidation of α,β-unsaturated esters, but in some cases also by reaction of α-oxo carboxylic esters with diazomethane.