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Factors Affecting Conformation in Proline-Containing Peptides
Taylor, Carol M.,Hardre, Renaud,Edwards, Patrick J. B.,Park, Jae H.
, p. 4413 - 4416 (2007/10/03)
(Equation presented) NMR was used to study the thermodynamics of the cis → trans isomerization for prolyl amide bonds in the compounds shown. The magnitude of Kt/c for C-terminal esters is greater than for the corresponding amides, signifying s
