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66485-00-5

[PtMe(p-tolyl)(1,5-cyclooctadiene)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 66485-00-5 Structure

  • Basic information

    1. Product Name: [PtMe(p-tolyl)(1,5-cyclooctadiene)]
    2. Synonyms:
    3. CAS NO:66485-00-5
    4. Molecular Formula:
    5. Molecular Weight: 409.431
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 66485-00-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [PtMe(p-tolyl)(1,5-cyclooctadiene)](CAS DataBase Reference)
    10. NIST Chemistry Reference: [PtMe(p-tolyl)(1,5-cyclooctadiene)](66485-00-5)
    11. EPA Substance Registry System: [PtMe(p-tolyl)(1,5-cyclooctadiene)](66485-00-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 66485-00-5(Hazardous Substances Data)

66485-00-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 66485-00-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,6,4,8 and 5 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 66485-00:
(7*6)+(6*6)+(5*4)+(4*8)+(3*5)+(2*0)+(1*0)=145
145 % 10 = 5
So 66485-00-5 is a valid CAS Registry Number.

66485-00-5Relevant articles and documents

Selectivity in reactions of alkyl-aryl-transition-metal complexes with electrophiles

Jawad, Jaafar K.,Puddephatt, Richard J.,Stalteri, Maria A.

, p. 332 - 337 (2008/10/08)

The new methylarylmetal complexes cis-[AuMe2Ph(PPh3)], cis-[AuMe2(4-MeC6H4)(PPh3)], [PtMe(4-MeC6H4)(C8H12)], cis-[PtMePh(PMePh2)2], and cis-[PtMe(4-MeC6H4)(PMe2Ph)2] have been prepared and characterized. In reactions with electrophilic reagents such as HCl, HgCl2, and [PtI2(PMe2Ph)2], the complexes undergo selective cleavage of a methyl-metal bond (e.g., cis-[PtMePh(PMePh2)2]) or an aryl-metal bond (e.g., cis-[AuMe2Ph(PPh3)], [PtMe(4-MeC6H4)(C8H12)]). From the selectivity observed and from studies of relative rates of reaction, it is argued that the SE2 mechanism leads to selective aryl-metal bond cleavage and that a different mechanism, probably involving an oxidative-addition-reductive-elimination sequence, leads to selective methyl-metal bond cleavage.

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