66512-22-9

Basic information

• Product Name: (1α,4Z,8α)-9-Azabicyclo[6.1.0]non-4-ene
• Synonyms: (1α,4Z,8α)-9-Azabicyclo[6.1.0]non-4-ene
• CAS NO: 66512-22-9
• Molecular Formula: C8H13N
• Molecular Weight: 123.19552
• Mol File: 66512-22-9.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (1α,4Z,8α)-9-Azabicyclo[6.1.0]non-4-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (1α,4Z,8α)-9-Azabicyclo[6.1.0]non-4-ene(66512-22-9)
• EPA Substance Registry System: (1α,4Z,8α)-9-Azabicyclo[6.1.0]non-4-ene(66512-22-9)

Safety Data

• Hazardous Substances Data: 66512-22-9(Hazardous Substances Data)

Upstream product

• 117468-08-3 (Z)-(1S,8R)-9-oxabicyclo[6.1.0]non-4-ene 
• 5259-72-3 cyclo-octa-1,5-diene 
• 1552-12-1 1,5-cis,cis-cyclooctadiene 

Relevant articles and documents

Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination

Cu(II)-mediated direct NH2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh2 catalysts and, in some instances, display important differences with comparable Rh2- and Fe-supported reactions.

Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids

A RhII-catalyzed direct and stereospecific N-H- and N-alkyl aziridination of olefins is reported that uses hydroxylamine-O-sulfonic acids as inexpensive, readily available, and nitro group-free aminating reagents. Unactivated olefins, featuring a wide range of functional groups, are converted into the corresponding N-H or N-alkyl aziridines in good to excellent yields. This operationally simple, scalable transformation proceeds efficiently at ambient temperature and is tolerant towards oxygen and trace moisture.