66512-56-9

Basic information

• Product Name: (3S,7aα)-Octahydro-3,6,7,7-tetramethyl-3aβ,6β-ethano-3aH-inden-5β-ol
• Synonyms: (3S,7aα)-Octahydro-3,6,7,7-tetramethyl-3aβ,6β-ethano-3aH-inden-5β-ol;Khusiol
• CAS NO: 66512-56-9
• Molecular Formula: C15H26O
• Molecular Weight: 222.36634
• Mol File: 66512-56-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 274.1°Cat760mmHg
• Flash Point: 114.2°C
• Appearance: /
• Density: 1g/cm³
• Vapor Pressure: 0.000702mmHg at 25°C
• Refractive Index: 1.519
• CAS DataBase Reference: (3S,7aα)-Octahydro-3,6,7,7-tetramethyl-3aβ,6β-ethano-3aH-inden-5β-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,7aα)-Octahydro-3,6,7,7-tetramethyl-3aβ,6β-ethano-3aH-inden-5β-ol(66512-56-9)
• EPA Substance Registry System: (3S,7aα)-Octahydro-3,6,7,7-tetramethyl-3aβ,6β-ethano-3aH-inden-5β-ol(66512-56-9)

Safety Data

• Hazardous Substances Data: 66512-56-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H26O/c1-10-5-6-11-13(2,3)14(4)7-8-15(10,11)9-12(14)16/h10-12,16H,5-9H2,1-4H3/t10-,11+,12+,14+,15-/m0/s1

Upstream product

• 139686-92-3 khusione 
• 1372617-30-5 C₁₅H₂₆O₂ 
• 1372617-32-7 C₂₂H₂₈O₃ 
• 1372617-31-6 C₁₅H₂₄O₂ 
• 1372617-29-2 C₁₈H₃₀O₂ 
• 139640-14-5 Formic acid (3aR,6S,7aR)-3,6,7,7-tetramethyl-1,4,5,6,7,7a-hexahydro-3a,6-ethano-inden-9-yl ester 
• 139640-15-6 (1S,5R,7R,8R)-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-en-8-ol 
• 139686-92-3 (1R,2S,5R,7R)-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undecan-8-one 
• 139686-91-2 (1R,2S,5R,7R,8R)-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undecan-8-ol 
• 139640-19-0 (1S,2R,3R,5R,7R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-3-yl methanesulfonate 
• 139640-20-3 (1S,2R,5R,7R,8S)-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undecan-3-one 
• 139640-17-8 (1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene 
• 139640-18-9 (1S,2R,3R,5R,7R, 8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undecan-3-ol 
• 139640-15-6 (1S,5R,7R,8S)-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-en-8-ol 

Downstream Products

• 139686-90-1 (1R,2S,5R,7R,8S)-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undecan-8-ol 
• 50657-30-2 Epikhusiol 

Relevant articles and documents

Approaches to the neurotrophically active natural product 11-O-debenzoyltashironin: A chemoenzymatic total synthesis of the structurally related sesquiterpene khusiol

Soothes your nerves: The enantiomerically enriched cis-1,2-dihydrocatechol 4 has been converted, over 16 steps including one involving an intramolecular Diels-Alder reaction, into the sesquiterpenoid natural product khusiol (3), which is structurally related to the neurite outgrowth-promoting natural product 11-O-debenzoyltashironin (1).

The Biogenetic-Type Cyclization of the Unsaturated Monocyclic Alcohol with Formic Acid; Factile Synthesis of the Tricarbocyclic Alcohol, (+)-2-Epi-allo-cedrol

The biogenetic-type cyclization of (+)-(3S)-2-(3-hydroxy-3-methyl-4-pentenyl)-1-methyl-3-(1-methylethenyl)-cyclopentene, prepared from d-limonene, with formic acid gave stereo and regiospecifically the formates of the tricyclic compounds of the allo-cedro