66522-78-9 Usage
Uses
Used in Research Applications:
Cyclohexanol-d12 is used as an isotopically labeled research compound for various scientific studies. Its deuterated nature allows for enhanced sensitivity and specificity in analytical techniques such as nuclear magnetic resonance (NMR) spectroscopy, making it a valuable tool for investigating molecular structures and dynamics.
Used in Chemical Synthesis:
Cyclohexanol-d12 serves as a precursor in the synthesis of various organic compounds, including nylon, a widely used polymer with applications in textiles, plastics, and other materials. Its use in chemical synthesis contributes to the development of new materials and products with improved properties.
Used in General Organic Chemistry:
As a general organic chemical solvent, cyclohexanol-d12 is utilized in various chemical reactions and processes. Its unique properties, such as its deuterated nature, make it suitable for specific applications where traditional solvents may not be as effective or efficient.
Check Digit Verification of cas no
The CAS Registry Mumber 66522-78-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,6,5,2 and 2 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 66522-78:
(7*6)+(6*6)+(5*5)+(4*2)+(3*2)+(2*7)+(1*8)=139
139 % 10 = 9
So 66522-78-9 is a valid CAS Registry Number.
InChI:InChI=1/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2/i1D2,2D2,3D2,4D2,5D2,6D,7D
66522-78-9Relevant academic research and scientific papers
Catalytic oxidation of hydrocarbons with O2 or H2O2 using a sterically hindered ruthenium complex
Goldstein, Alan S.,Beer, Robert H.,Drago, Russell S.
, p. 2424 - 2429 (2007/10/02)
The sterically hindered complex cis-[Ru(dmp)2(S)2](PF6)2 (S = H2O; CH3CN), where dmp is 2,9-dimethyl-1,10-phenanthroline, catalyzes the oxidations of alkenes with dioxygen and of alkanes with hydrogen peroxide under mild pressures (40-50 psig) and temperatures (65-75 °C). The reaction of norbornene, O2, and a catalytic amount of [Ru(dmp)2(CH3CN)2] (PF6)2 results in 2,3-epoxynorbornane with 94% selectivity. Mechanistic experiments suggest that a free-radical reaction between cis-[Ru(dmp)2(CH3CN)2](PF6) 2, norbornene, and O2 occurs initially to generate a high-valent ruthenium oxo species involved in an oxygen atom-transfer catalytic cycle with O2. In the presence of H2O2 and a catalytic amount cis-[Ru(dmp)2(S)2](PF6)2 (S = H2O; CH3CN), unactivated alkanes are hydroxylated. Studies of this reaction indicate a free-radical mechanism in which H atom abstraction is the rate-determining step (kH/kD = 4 for cyclohexane).
