66529-33-7Relevant academic research and scientific papers
Microbiological Reduction of Cyclohexenones by Growing Clostridium Cells
Bostmembrun-Desrut, M.,Kergomard, A.,Renard, M. F.,Veschambre, H.
, p. 1997 - 2000 (2007/10/02)
2-Deuterio-2-cyclohexen-1-one, 3-deuterio-2-cyclohexen-1-one and 2-methyl-2-cyclohexen-1-one were reduced by Clostridium La 1 giving a single bioconversion product resulting from reduction of the carbon-carbon double bond.Stereochemistry of the reaction was studied.
Optical Rotatory Dispersion Studies. 133. Deuterium Octant Contributions in Cyclohexanones
Sundararaman, P.,Barth, Guenter,Djerassi, Carl
, p. 5231 - 5236 (2007/10/02)
The synthesis of four conformationally rigid monodeuterium-substituted cyclohexanones, (2R,4R)-4-isopropyl(2-2H1)cyclohexanone (1), (2S,4R)-4-isopropyl(2-2H1)cyclohexanone (2), (3R,4R)-4-tert-butyl(3-2H1)-cyclohexanone (3), and (3S,4R)-4-tert-butyl(3-2H1)
Microbiological Synthesis of Optically Active 3-Deuterio-cycloalkanones
Dauphin, Gerard,Gramain, Jean-Claude,Kergomard, Alain,Renard, Michel F.,Veschambre, Henri
, p. 318 - 319 (2007/10/02)
Optically active 3-deuterio-cyclopentanone and 3-deuterio-cyclohexanone have been prepared by microbiological reduction of 3-deuterio αβ-unsaturated cyclic ketones by Beauveria sulfurescens.
