66605-84-3Relevant articles and documents
LACTONIZATION REACTIONS OF (Ω-CARBOXYALKYL)SULFONIUM SALTS
Nakamura, Takako,Matsuyama, Haruo,Takahashi, Masaya,Kamigata, Nobumasa
, p. 59 - 66 (2007/10/02)
The intramolecular cyclizations of sulfonium salts having an ω-carboxyalkyl group were investigated for the synthesis of five- to nine-membered lactones, and five- to seven-membered lactones were obtained in good yields from S-(ω-carboxyalkyl)thiolanium salts.The scope and limitations of the synthetic utility of the reaction are indicated by this study. Key words: Lactonization reactions; (ω-carboxyalkyl)diphenylsulfonium salts; S-(ω-carboxyalkyl)thiolanium salts; medium-sized lactones; large-sized lactones; sulfur-containing lactones.
