6664-99-9

Basic information

• Product Name: 2-deoxy-lyxo-hexose
• Synonyms: 2-deoxy-lyxo-hexose
• CAS NO: 6664-99-9
• Molecular Formula: C₆H₁₂O₅
• Molecular Weight: 164.16
• Mol File: 6664-99-9.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 480°C at 760 mmHg
• Flash Point: 250.8°C
• Appearance: /
• Density: 1.429g/cm³
• Vapor Pressure: 3.13E-11mmHg at 25°C
• Refractive Index: 1.556
• CAS DataBase Reference: 2-deoxy-lyxo-hexose(CAS DataBase Reference)
• NIST Chemistry Reference: 2-deoxy-lyxo-hexose(6664-99-9)
• EPA Substance Registry System: 2-deoxy-lyxo-hexose(6664-99-9)

Safety Data

• Hazardous Substances Data: 6664-99-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H14O5/c7-2-1-4(9)6(11)5(10)3-8/h4-11H,1-3H2/t4-,5-,6-/m1/s1

Upstream product

• 4949-20-6 (E)-2,4-pentadien-1-ol 
• 63780-11-0 trans-2,4-pentadienyl acetate 
• 104048-36-4 Acetic acid (E)-3-(4,5-dihydro-isoxazol-5-yl)-allyl ester 
• 104048-45-5 Acetic acid (2S,3R)-3-(S)-4,5-dihydro-isoxazol-5-yl-2,3-dihydroxy-propyl ester 
• 104048-45-5 Acetic acid (2S,3R)-3-(R)-4,5-dihydro-isoxazol-5-yl-2,3-dihydroxy-propyl ester 

Relevant articles and documents

SILYL NITRONATES AND NITRILE OXIDES IN ORGANIC SYNTHESIS. A NOVEL ROUTE TO D,L-DEOXYSUGARS. USE OF ALUMINIUM OXIDE AS SOLID PHASE BASE FOR GENERATION OF NITRILE OXIDES FROM HYDROXIMIC ACID CHLORIDES

Novel methodology is developed for a three step synthesis of deoxyaldoses and deoxyketoses. 1.Regioselective addition of silyl nitronate or nitrile oxide to a diene. 2.Stereospecific hydroxylation of the double bond. 3.Unmasking of the aldol moiety by catalytic reduction of the 2-isoxazoline.The syntheses of D.L-deoxyribose, D,L-oleose, D,L-digitoxose, D,L-2-deoxygalactose, 1,3-dideoxyfructose, 3-deoxyfructose etc. are described.Basic aluminium oxide is introduced as a solid phase base for the one step synthesis of 2-isoxazolines from aldoximes and olefins.An X-ray diffraction study of compound 13c verifies the stereochemical assignments.