66655-46-7Relevant academic research and scientific papers
Silicon mediated synthesis and selected transformations of β-chloroketones
Salama, Tarek A.,Elmorsy, Saad S.
experimental part, p. 1171 - 1174 (2012/01/05)
A combination of tetrachlorosilane (TCS) and phenol in dichloromethane was found to be an efficient reagent for hydrochlorination of α,β- unsaturated ketones to afford the corresponding β-chloroketones in good yield at ambient temperature. Reactions of th
Improved Schmidt synthesis of 1,5-disubstituted 1H-tetrazoles from ketones
Suzuki,Hwang,Nakaya,Matano
, p. 1218 - 1220 (2007/10/02)
On treatment with an excess of sodium azide in the presence of titanium(IV) chloride in boiling acetonitrile, both aliphatic and aromatic ketones are smoothly converted to 1,5-disubstituted 1H-tetrazoles in high yields.
STRUCTURE AND PROPERTIES OF THE PRODUCT OF BROMINATION OF STYRYLTETRAZOLE
Postovskii, I. Ya.,Zyryanov, V. A.,Rusinov, V. L.,Klyuev, N. A.,Aleksandrov, G. G.,et al.
, p. 454 - 457 (2007/10/02)
It was shown by means of x-ray diffraction analysis, NMR spectroscopy, and mass spectrometry that, regardless of its phase state, 1-(1'-phenyl-5'-tetrazolyl)-2-phenyl-1,2-dibromoethane (II) exists in the form of the threo conformer (the erythro form is also observed in the gas phase).The thermolysis of II is accompanied by facile splitting out of a molecule of bromine.
