666740-75-6

Upstream product

• 6485-40-1 (R)-Carvone 
• 127969-63-5 methyl 2-[(1S,6R)-6-isopropenyl-3-methyl-2-oxocyclohex-3-enyl]acetate 

Downstream Products

• 666740-73-4 methyl 2-[(1S,2R,6R)-6-isopropenyl-2-methoxy-3-methyl-cyclohex-3-en-1-yl]acetate 
• 1236216-13-9 methyl 2-[(1S,2R,6R)-2-(methoxymethoxy)-3-methyl-6-(1-methylethenyl)cyclohex-3-enyl]acetate 
• 776306-98-0 ((1S,2R,6R)-6-Isopropenyl-2-methoxy-3-methyl-cyclohex-3-enyl)-acetic acid 

Relevant academic research and scientific papers

Enantiospecific synthesis of the tricyclic core structure of lippifolianes

An enantiospecific synthesis of the [6.6.3]-tricyclic carbon framework, 2,6,6,9-tetra-methyltricyclo[5.4.0.02,4]undecane, present in the sesquiterpenes lippifolianes and the diterpenes cyclosclareol, metasequoic acids and parguerols, starting f

Enantiospecific synthesis of (+)-trans-α-himachalene via an intramolecular type II carbonyl ene reaction

Enantiospecific synthesis of (+)-trans-α-himachalene starting from (R)-carvone is described. An intramolecular type II carbonyl ene reaction has been employed as the key step for the construction of the bicyclo[5.4.0]undecane ring system.

Carbanion cyclisation of esters. Part 2: Enantiospecific construction of the tricyclic framework of the marine sesquiterpenes, spirodysins

Enantiospecific construction of the bicyclo[4.3.0]nonan-8-one 17 employing a lithium and liquid ammonia mediated carbanion cyclisation of the δ-methyl-δ,ε-unsaturated ester 13, and its elaboration to the tricyclic framework of the marine sesquiterpenes sp

Enantiospecific first total synthesis of (+)-trans-α-himachalene

An enantiospecific first total synthesis of (+)-trans-α-himachalene, one of the eight male specific sesquiterpenes isolated from the crucifer flea beetle Phyllotreta cruciferae, starting from the readily and abundantly available monoterpene, (R)-carvone,