66730-31-2Relevant academic research and scientific papers
Visible light-induced hydroxyalkylation of 2H-benzothiazoles with alcohols via selectfluor oxidation
Kong, Yaolei,Xu, Wenxiu,Liu, Xinghai,Weng, Jianquan
supporting information, p. 3245 - 3249 (2020/06/21)
A visible-light induced metal-free approach was described for the hydroxyalkylation of 2H-benzothiazoles with alcohols by using selectfluor as the oxidant. A variety of 2H-benzothiazoles and alcohols could be tolerated, providing a mild and simple method for the synthesis of C2-hydroxyalkylated 2H-benzothiazoles in moderate to good yields. Besides, ethers were also compatible in this reaction, leading to corresponding C2 ether-substituted 2H-benzothiazoles with high regioselectivity.
Direct C2-alkylation of azoles with alcohols and ethers through dehydrogenative cross-coupling under metal-free conditions
He, Tao,Yu, Lin,Zhang, Lei,Wang, Lei,Wang, Min
supporting information; experimental part, p. 5016 - 5019 (2011/11/12)
A metal-free novel, simple, and highly efficient method for the direct C2-alkylation of azoles with alcohols and ethers has been developed on the basis of an oxidative C-H activation process. The dehydrogenative C-C cross-coupling reactions of R-position
