66751-86-8Relevant academic research and scientific papers
CHEMISTRY OF OXALYL DERIVATIVES OF METHYL KETONES. XXXV. KINETICS OF THE FORMATION OF 3-PHENACYLIDENE-3,4-DIHYDRO-2-QUINOXALONES FROM ARYLAMIDES OF AROYLPYRUVIC ACIDS AND o-PHENYLENEDIAMINE
Andreichikov, Yu.S.,Kozlov, A.P.,Kurdina, L.N.
, p. 752 - 756 (2007/10/02)
The kinetics of the acid-catalyzed reactions of the arylamides of aroylpyruvic acids with o-phenylenediamine, leading to the formation of 3-phenacylidene-2-quinoxalones, were investigated.It was established that the reaction rate is controlled by nucleophilic attack by the amide carbonyl at the cyclization stage.
