66767-24-6

Upstream product

• 491-04-3 trans-6-isopropyl-3-methylcyclohex-2-en-1-ol 
• 73335-40-7 (2S,3S,6R)-2,3-Dihydroxy-6-isopropyl-3-methyl-cyclohexanone 
• 75316-41-5 3,5-dinitro-benzoic acid-((3RS,4SR)-p-menth-1-en-3-yl ester) 
• 75316-41-5 3,5-dinitro-benzoic acid-((3RS,4RS)-p-menth-1-en-3-yl ester) 
• 73335-40-7 (2S,3S,6S)-2,3-Dihydroxy-6-isopropyl-3-methyl-cyclohexanone 
• 89-81-6 piperitone 
• 75316-43-7 3,5-Dinitro-benzoic acid (1R,2R,3S,6S)-2,3-dihydroxy-6-isopropyl-3-methyl-cyclohexyl ester 
• 75316-43-7 3,5-Dinitro-benzoic acid (1R,2S,3R,6R)-2,3-dihydroxy-6-isopropyl-3-methyl-cyclohexyl ester 
• 75316-43-7 3,5-Dinitro-benzoic acid (1R,2S,3R,6S)-2,3-dihydroxy-6-isopropyl-3-methyl-cyclohexyl ester 

Relevant academic research and scientific papers

Molybdenum-catalyzed diastereoselective anti-dihydroxylation of secondary allylic alcohols

In this protocol, we report a Mo-catalyzed anti-dihydroxylation of secondary allylic alcohols, providing a general method for the preparation of 1,2,3-triols bearing up to three continuous stereocenters with excellent diastereocontrol. The mechanistic studies reveal that this dihydroxylation reaction consists of two steps and up to excellent diastereomeric ratios of the final triol products can be achieved due to the high level of both diastereocontrol in the initial epoxidation and regiocontrol in the following hydrolysis in situ.

SYNTHESIS OF 1,2,3-TRIHYDROXY-p-MENTHANES

Seven new stereoisomers of 1,2,3-trihydroxy-p-menthane have been synthesised.Their stereochemistry, proved mainly via chemical transformations and confirmed by (1)H-NMR, is discussed.