66778-00-5Relevant academic research and scientific papers
Catalytic one-pot synthesis of N-phenyl alkyl amides from alkene and aniline in the presence of cobalt on charcoal under carbon monoxide
Lee, Sang Ick,Son, Seung Uk,Chung, Young Keun
, p. 1310 - 1311 (2002)
N-Phenyl alkyl amides were synthesized by the cobalt on charcoal-catalyzed one-pot reaction of alkene and aniline under carbon monoxide; this is the first heterogeneous catalytic formation of N-phenyl alkyl amides.
Reductive amidation of alkyl tosylates with isocyanates by a Ni/Co-dual catalytic system
Michiyuki, Takuya,Osaka, Itaru,Komeyama, Kimihiro
supporting information, p. 1247 - 1250 (2020/02/04)
Reductive amidation of alkyl tosylates with isocyanates using the Ni/Co-dual catalytic system is disclosed. The method proceeds efficiently under mild conditions, giving rise to the corresponding alkyl amides. Notably, the protocol can discriminate the steric environment of two alkyl tosylate moieties, enabling regioselective mono-amidation at the less-bulky site.
Organic ligand-free carbonylation reactions with unsupported bulk Pd as catalyst
Liu, Shujuan,Wang, Hongli,Dai, Xingchao,Shi, Feng
supporting information, p. 3457 - 3462 (2018/08/06)
Herein, surprising results for bulk Pd-catalyzed carbonylation reactions are presented. Three types of carbonylation reactions can be realized efficiently under organic ligand-free conditions, namely, hydroaminocarbonylation of olefins, aminocarbonylation of aryl iodides and oxidative carbonylation of amines, which almost cover all the known mechanisms in carbonylation reactions. Notably, the bulk Pd catalyst system exhibited better catalytic activity than the classical homogeneous PdCl2/(2-OMePh)3P catalyst system. This study will create a momentous and new field of green carbonylation reactions.
