6681-02-3Relevant academic research and scientific papers
DIVINYL SULFIDE. XIV. DIVINYL SULFIDE AND SULFUR-CONTAINING HETEROCYCLES FROM VINYL HALIDES AND SODIUM SULFIDE
Trofimov, B. A.,Amosova, S. V.,Nosyreva, V. V.,Voronkov, M. G.
, p. 2123 - 2127 (2007/10/02)
The reaction of vinyl halides with hydrated sodium sulfide in the potassium hydroxide-DMSO (HMDTA) superbasic system leads to the formation of divinyl sulfide, 2,5-dimethyl-4-methylene-1,3-oxathiolane, 2,4,5-trimethyl-1,3-oxathiole, and 2-thiabicyclohept-3-ene and also dimethyl sulfide, vinyl methyl sulfide, and vinyl ethyl sulfide.The effect of the reaction conditions (temperature, solvent, time, and ratio of reagents) on the yield of the products and the selectivity of the process was studied.
