66871-26-9Relevant articles and documents
Reaction of Dialkyl Phosphites with α-Enones. I. - Synthesis and Allylic Rearrangement of Dimethyl (1-Hydroxy-2-alkenyl)- and (1-Hydroxy-2-cycloalkenyl)phosphonates
Oehler, Elisabeth,Zbiral, Erich
, p. 175 - 184 (2007/10/02)
Various β,γ-unsaturated α-hydroxyphosphonates 3 are prepared in good yields by NaOCH3-catalyzed regioselective 1,2-addition of dimethyl phosphite to acyclic and cyclic α-enones at -35 deg C.On acid-catalyzed acetylation, the allylic α-hydroxyphosphonates
