66891-06-3Relevant academic research and scientific papers
Regioselective synthesis of fatty acid esters of methyl α-D-glucopyranoside with dibutyltin dimethoxide method and biological test against staphylococcus aureus and salmonella agona
Lou, Xin,O'Brien, Julie,Henehan, Gary,Cassidy, Seamas
experimental part, p. 3135 - 3146 (2010/11/05)
Fatty acid esters of methyl α-D-glucopyranoside were regioselectively synthesized using dibutyltin dimethoxide (DBDM) as stannylating agent, general factors affecting regioselectivity has been examined. Comparison work indicated that DBDM has some advantage as stannylating agent over dibutyltin oxide for regioselective acylation at the 2-position of unprotected methyl α-D-glucopyranoside. Microbiological tests show that methyl 2-lauryl-α-D-glucopyranoside is effective inhibitor against gram-negative bacterial Staphylococcus aures.
SUGAR CHEMISTRY WITHOUT PROTECTING GROUPS-III. A FACILE CHEMICAL SYNTHESIS OF 6-O-ACYL-D-GLYCOPYRANOSES AND METHYL-6-O-ACYL-D-GLYCOPYRANOSIDES.
Baczko, Krystyna,Plusquellec, Daniel
, p. 3817 - 3828 (2007/10/02)
Regioselective acylation of non protected glycopyranosides was performed using 3-acylthiazolidine-2-thiones 1 and the novel 3-acyl-5-methyl-1,3,4-thiadiazole-2(3H)-thiones 2 as the acylating reagents, yielding 6-O-acylated derivatives in high yields.Acyla
