669048-59-3Relevant academic research and scientific papers
Isolation and Ring-Opening of New 1-Sila-3-metallacyclobutanes (η 5-C5H4Fe)(CO)2CH2SiR 2 Leading to A New Class of Organometallic Polymer
Sharma, Hemant K.,Cervantes-Lee, Francisco,Pannell, Keith H.
, p. 1326 - 1327 (2004)
Treatment of FpCH2SiR2Cl [Fp = (η5-C5H5)Fe(CO)2] with lithium diisopropylamide leads to the formation of new metallacycle complexes. When R2 = Me2 and MenBu, these ring-open to form a new class of organometallic polymer. When R2 = nBu2, the metallacycle resists ring-opening and may be structurally characterized as the Ph3P-substituted species. Copyright
