669090-24-8Relevant academic research and scientific papers
Regioselectivity and memory effects in palladium catalyzed allylic alkylations with bidentate P^PS donor ligands
Milheiro, Suzanna C.,Faller
, p. 879 - 886 (2011/03/21)
A series of complexes, [Pd(η3-C3H 5)(P^PS)][SbF6], where P^PS are bidentate bisphosphine monosulfide ligands, were found to catalyze allylic alkylation reactions with high branched:linear selectivity with some ligands. Some of these catalysts also display a regiochemical memory effect, in which the hemilability and rigidity of the P^PS ligands affect the reaction rate and the degree to which a memory effect is observed.
