66953-84-2

Upstream product

• 22220-85-5 1,2-dilithio-o-carborane 
• 644-97-3 Dichlorophenylphosphine 
• 16872-09-6 1,2-dicarba-closo-dodecaborane⁽¹²⁾ 

Downstream Products

• 97999-96-7 1,1':2.2'-bis-μ-phenylphosphino-bis[1,2-dicarba-closo-dodecaborane(12)] 
• 210905-08-1 1-phenylphosphino-1,2-dicarba-closo-dodecaborane⁽¹²⁾ 
• 97136-56-6 4,5-dicarba-closo-dodecaboranyl-1-aza-2,5-diphospholane 
• 1610618-88-6 C₂₀H₃₁B₁₀P₃ 
• 1610618-86-4 C₂₀H₂₅B₁₀P₃ 
• 210905-14-9 1,2-bis(phenylthiophosphoryl)-1,2-dicarba-closo-dodecaborane⁽¹²⁾-dithiodiphosphinic acid 
• 207723-56-6 1,2-bis(phenylphosphanyl)-1,2-dicarba-closododecaborane⁽¹²⁾ 
• 96732-55-7 1.2-(P(C₆H₅)N₃)2-1.2-C₂B₁₀H₁₀ 

Relevant academic research and scientific papers

The reaction of phenylchlorophosphino-substituted 1,2-dicarba-closo-dodecaboranes(12) with elemental sulfur and molecular structures of rac-1,2-bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12) and 1-phenylchlorothiophosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

rac-1,2-Bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12) (1) reacts with four equivalents of sulfur at 185-190°C in undecane to give the cyclic anhydride of 1,2-bis(phenylthiophosphoryl)-1,2-dicarba-closo-dodecaboranyl(12)- dithiodiphosphinic acid (2). Under comparable conditions, 1-phenyl-chlorophosphino-1,2-dicarba-closo-dodecaborane(12) (4) and 1-phenyl-chlorophosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12) (5) react with sulfur to give 1-phenylchlorothiophosphino-1,2-dicarba-closo-dodecaborane(12) (6) and 1-phenylchlorothiophosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12) (7). Compounds 4-7 were characterized by 1H, 31P, 13C and 11B NMR spectroscopy and elemental analysis, and X-ray structure determinations were carried out on 1 and 7.

Chemistry of decaborane-phosphorus compounds. IV. Monomeric, oligomeric, and cyclic phosphinocarboranes

Dilithiocarborane, B10H10C2Li2, was allowed to react with chlorophosphines containing one, two, and three chlorine atoms. (C6H5)2PCl and C6H5PCl2 gave the expected disubstituted compounds, B10H10C2[P(C6H5) 2]2 and B10H10C2(C6H 5P·Cl)2, respectively. B10H10C2Li2 and PCl3, however, formed a compound having two phosphorus atoms and two carborane nuclei in a six-membered ring. This unique ring system also arose from the reaction of B10H10C2Li2 with B10H10C2(C6H 5P·Cl)2. Subsequent reactions of such molecules with ammonia and NaN3 are described. The cyclic bis-azide, (B10H10C2P·N3)2. and p-[(C6H5)2P]2C6H 4 reacted to form a PNP bonded oligomer.