66967-47-3

Basic information

• Product Name: Benzene, [(1Z)-1-heptenylthio]-
• CAS NO: 66967-47-3
• Molecular Formula: C13H18S
• Molecular Weight: 206.352
• Mol File: 66967-47-3.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [(1Z)-1-heptenylthio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1Z)-1-heptenylthio]-(66967-47-3)
• EPA Substance Registry System: Benzene, [(1Z)-1-heptenylthio]-(66967-47-3)

Safety Data

• Hazardous Substances Data: 66967-47-3(Hazardous Substances Data)

Upstream product

• 30536-77-7 <(phenylthio)(trimethylsilyl)methyl>lithium 
• 66-25-1 hexanal 
• 63318-29-6 (Z)-1-iodohept-1-ene 
• 90496-82-5 2-iodohept-1-ene 
• 882-33-7 diphenyldisulfane 
• 628-71-7 1-Heptyne 
• 108-98-5 thiophenol 
• 66967-42-8 (Z)-Hept-1-en-1-yl-phenyl-sulfoxid 

Relevant articles and documents

A simple and general preparation of vinylic sulfides, selenides and tellurides

A general method for the synthesis of vinylic chalcogenides by nucleophilic and Ni-catalyzed vinylic substitution on vinylic halides by phenyl chalcogenolates is described. The reactions were regio and stereoselective for the nickel catalyzed substitution

Nickel(II) chloride-catalyzed regioselective hydrothiolation of alkynes

Regioselective Markovnikov-type addition of PhSH to alkynes (HC≡C-R) has been performed using easily available nickel complexes. The non-catalytic side reaction leading to anti-Markovnikov products was suppressed by addition of γ-terpinene to the catalyti

Alkenyl-copper derivatives 20. Preparation of polysubstituted conjugated dienes by coupling of alkenyl halides with alkenyl copper reagents

Magnesio associated vinyl-copper derivatives, obtained by carbocupration of terminal alkynes, couple with 1-halo-1-elkenes, in the presence of Pd(PPh3)4 as catalyst, to afford polysubstituted conjugated dienes in high yield and excellent stereoisomeric purity.

VINYL-COPPER DERIVATIVES 15 : AN EFFICIENT SYNTHESIS OF POLYSUBSTITUTED CONJUGATED DIENES

Magnesium vinyl-copper derivatives, obtained by carbocupration of terminal alkynes, couple with 1-halo-1-alkenes, in the presence of Pd(PPh3)4 catalyst, to afford polysubstituted conjugated dienes in high yield and excellent stereoisomeric purity.

REACTIONS OF PHENYLTHIOTRIMETHYISILYLMETHYLLITHIUM: PREPARATION OF α-PHENYLTHIOKETONES AND ADDITIONS TO 2-CYCLOHEXEN-1-ONE

Phenylthiotrimethylsilylmethyllithium(1) was reacted with a variety of electrophiles, including some containing two functional groups. α-Phenylthioketones were obtained from the reaction with esters.The anion(1) underwent either 1,2- or 1,4-addition, depe