670223-06-0Relevant academic research and scientific papers
Highly stereoselective C-allylation of an enantiopure α-sulfinyl thioacetamide
Nowaczyk, Stephanie,Alayrac, Carole,Metzner, Patrick,Averbuch-Pouchot, Marie-Therese
, p. 6852 - 6855 (2002)
The alkylation of the lithium enolate of enantiopure α-cyclohexylsulfinyl thioacetamide 1 with allyl bromides 5 possessing an electron-withdrawing group at the vinylic position does not occur at the sulfur center - as expected in the sulfur series - but a
Studies directed towards the enantioselective synthesis of ethisolide and isoavenaciolide
Blot, Virginie,Reboul, Vincent,Metzner, Patrick
, p. 1934 - 1939 (2007/10/03)
An asymmetric synthesis of an analog of ethisolide has been achieved by using as key steps two σ[3,3]rearrangements stereocontrolled by a sulfinyl group. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
Asymmetric Induction of the Iodolactonization Reaction of α-Sulfurated γ-Unsaturated Amides
Blot, Virginie,Reboul, Vincent,Metzner, Patrick
, p. 1196 - 1201 (2007/10/03)
The 1,3-asymmetric iodolactonization reaction of enantiopure α-sulfurated γ-unsaturated amides has been investigated. With sulfinyl and sulfonyl groups, a poorly stereoselective reaction was observed, whereas with a sulfanyl moiety, the diastereoselectivi
