670256-87-8

Basic information

• Product Name: [Rh(CO)Cl((C₆H₂OCH₂OP(C₆H₅)2)2)]
• CAS NO: 670256-87-8
• Molecular Weight: 776.954
• Mol File: 670256-87-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Rh(CO)Cl((C₆H₂OCH₂OP(C₆H₅)2)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(CO)Cl((C₆H₂OCH₂OP(C₆H₅)2)2)](670256-87-8)
• EPA Substance Registry System: [Rh(CO)Cl((C₆H₂OCH₂OP(C₆H₅)2)2)](670256-87-8)

Safety Data

• Hazardous Substances Data: 670256-87-8(Hazardous Substances Data)

Upstream product

• 210169-54-3 (R)-[C₆H₂OCH₂OP(C₆H₅)2]2 

Relevant articles and documents

Difluorphos, an Electron-Poor Disphosphane: A Good Match between Electronic and Steric Features

The π acidity makes the difference: The fluorinated diphosphane, difluorphos, is synthesized (see structure: purple = P, red = O, green = F, gray = C) and its stereoelectronic features are evaluated in theoretical and experimental studies. Its unusual π acidity explains the excellent results obtained with it in ruthenium-mediated asymmetric hydrogenation of fluorinated β-functionalized ketones. These results are better than those obtained with other biphenyl-based diphosphanes.