67067-91-8Relevant academic research and scientific papers
Rhodium-catalyzed intermolecular reaction of alkyl azides with diazo(aryl)acetates
Gu, Peiming,Wu, Xiu-Ping,Su, Yan,Li, Xue-Qiang,Xue, Ping,Li, Rui
, p. 535 - 538 (2014)
An efficient intermolecular interception of alkyl azides by diazo(aryl)acetates was achieved in the presence of dirhodium tetraoctanoate. The initial products were unstable α-imino esters, and overaddition of carbenoids to the C-N double bonds was avoided. After acidic workup, the corresponding α-keto esters were obtained in good to excellent yields. Georg Thieme Verlag Stuttgart New York.
