67087-51-8Relevant academic research and scientific papers
Direct Access to N -Alkylsulfoximines from Sulfides by a Sequential Imidation/Oxidation Procedure
Dannenberg, Carl Albrecht,Bizet, Vincent,Bolm, Carsten
, p. 1951 - 1959 (2015)
Synthetically relevant N-alkyl-substituted sulfoximines are directly prepared from sulfides by an unprecedented one-pot imidation/oxidation sequence. In situ generated N-bromoalkylamines serve as readily accessible imidating agents leading to N-alkylsulfiliminium bromides that are subsequently oxidized providing the corresponding N-alkylsulfoximines. In this manner, gram quantities of the products can be obtained in a short period of time avoiding the use of toxic and cumbersome to handle alkylating reagents.
