67088-60-2Relevant academic research and scientific papers
7. Tetrazinodiheteroarene: 'Charge -Transfer'-Komplexbildung mit Akzeptorverbindungen
Hellrung, Bruno,Balli, Heinz
, p. 81 - 85 (2007/10/02)
The formation of charge-transfer complexes and radical-ion pairs of donor compounds 1-6 with acceptor compounds 7-12 has been investigated by means of VIS/NIR-spectrospcopic methods.The equilibrium constants KCT (up to 1100M-1) for the donor/acceptor couple dipyridotetrazine (2)/ethylenetetracarbonitrile (11) and spectra of the CT complexes have been determined in 1,2-dichloroethane solution at 25 deg C.Results are discussed in relation to known CT-complex properties and to voltammetric redox-potentials E1/2.
