67113-49-9Relevant academic research and scientific papers
Ruthenium catalyzed synthesis of 2,3-unsaturated C-glycosides from glycals
Srinivas, Batthula,Reddy, Thurpu Raghavender,Kashyap, Sudhir
, p. 86 - 92 (2015)
A highly efficient and convenient C-glycosylation method was developed using ruthenium(III) chloride for the synthesis of 2,3-unsaturated C-glycosides. Various nucleophiles such as allyl trimethylsilane, triethylsilane, trimethylsilyl cyanide, trimethylsi
A mild and efficient Zn-catalyzed C-glycosylation: Synthesis of C(2)-C(3) unsaturated C-linked glycopyranosides
Reddy, Thurpu Raghavender,Rao, Dodla Sivanageswara,Kashyap, Sudhir
, p. 28338 - 28343 (2015/04/14)
A highly efficient C-glycosylation method was developed by using catalytic Zn(OTf)2 for the synthesis of 2,3-unsaturated C-glycosides. The scope of the protocol was well illustrated with different substituted glycals and nucleophiles comprising
ALLYLIC SUBSTITUTIONS IN TRI-O-BENZYL-GLYCALS, 4,6-OBENZYLIDENE-GLYCALS AND RELATED COMPOUNDS
Guthrie, R. D. (Gus),Irvine, Robert W.
, p. 225 - 236 (2007/10/02)
3,4,6-Tri-O-benzyl-D-glucal and the benzyl 4,6-di-O-benzyl-2,3-dideoxy-hex-2-enopyranosides react with sodium azide in acetonitrile under boron trifluoride catalysis to yield mixtures of 3-azido-glycals and 2,3-unsaturated glycosyl azides.Similar reaction
