671184-49-9Relevant articles and documents
Rapid Assembly of Polycyclic Substances by a Multicomponent Cascade (4 + 2)-(2 + 2) Cycloadditions: Total Synthesis of the Proposed Structure of Paesslerin A
Inanaga, Kazato,Takasu, Kiyosei,Ihara, Masataka
, p. 1352 - 1353 (2004)
A versatile method for stereoselective formation of multisubstituted bicyclo[4.2.0]octane framework has been developed by means of catalytic (4 + 2)-(2 + 2) cycloaddition reactions. Its application to the synthesis of a substance reported to be the cytotoxic sesquiterpene, paesslerin A, is described, and it has been made clear that a revision of the structure of natural paesslerin A is required. Copyright