671192-26-0Relevant academic research and scientific papers
Formation of Trinuclear Palladium Orthometalated Complexes with Unprecedented Asymmetrical (μ3-S)(μ3-X) Bridges (X = OH, SR, O2CR) from μ2-Hydroxo Dimeric Complexes and CS2
Espinet, Pablo,Hernandez, Celia,Martin-Alvarez, Jose M.,Miguel, Jesus A.
, p. 843 - 845 (2004)
Complexes [Pd3(μ3-S)(μ3-X)(L) 3] (L = orthometalated imine), obtained by an unusual reaction of μ2-OH dimeric complexes and CS2, are an unprecedented type of asymmetrical bridges between metallatriangles, which force an all-cis arrangement of the three orthometalated ligands relative to the metallatriangle.
