67213-36-9

Upstream product

• 100-44-7 benzyl chloride 
• 129155-91-5 (S)-3,4-dimethoxybutan-1-ol 
• 129155-92-6 2-[(S)-2-((S)-2,3-Dimethoxy-propyl)-[1,3]dioxolan-4-yl]-ethanol 
• 82780-41-4 (S)-4-benzyloxy-1,2-dimethoxy-butane 
• 129155-94-8 [(S)-2-((S)-2,3-Dimethoxy-propyl)-[1,3]dioxolan-4-yl]-acetaldehyde 
• 129155-96-0 1-[(S)-2-((S)-2,3-Dimethoxy-propyl)-[1,3]dioxolan-4-yl]-3-methyl-but-3-en-2-ol 
• 82780-40-3 (S)-(-)-3,4-dimethoxybutanal 
• 82796-92-7 (2R,6S)-2-((S)-2,3-Dimethoxy-propyl)-6-hydroxymethyl-3,3-dimethyl-tetrahydro-pyran-4-one 
• 129155-98-2 1-[(2S,4S)-2-((S)-2,3-Dimethoxy-propyl)-[1,3]dioxolan-4-yl]-3-methyl-but-3-en-2-one 
• 82780-42-5 (S)-4-(2-Benzyloxy-ethyl)-2-((S)-2,3-dimethoxy-propyl)-[1,3]dioxolane 
• 82796-93-8 Benzoic acid (2S,6R)-6-((S)-2,3-dimethoxy-propyl)-5,5-dimethyl-4-oxo-tetrahydro-pyran-2-ylmethyl ester 
• 129156-00-9 {1-[(2S,4S)-2-((S)-2,3-Dimethoxy-propyl)-[1,3]dioxolan-4-ylmethyl]-2-methyl-propenyloxy}-dimethyl-phenyl-silane 

Relevant academic research and scientific papers

Studies related to the synthesis of pederin. Part 2. Synthesis of pederol dibenzoate and benzoylpedamide

Syntheses of the ring B fragments (+)-pederol dibenzoate (2) and (±)-benzoylpedamide (3) of the insect toxin pederin (1) are described. An intramolecular directed aldol condensation was used to construct the tetrahydropyran ring in (+)-pederol dibenzoate