672285-12-0Relevant academic research and scientific papers
A highly nucleophilic multifunctional chiral phosphane-catalyzed asymmetric intramolecular rauhut-currier reaction
Zhang, Xiao-Nan,Shi, Min
supporting information, p. 6271 - 6279 (2013/01/15)
An asymmetric variant of the intramolecular Rauhut-Currier (RC) reaction can be achieved using a highly nucleophilic multifunctional chiral phosphane; the corresponding cyclopentene and cyclohexene derivatives are produced in moderate to good yields and w
Chemically Induced Anion Radical Cycloadditions: Intramolecular Cyclobutanation of Bis(enones) via Homogeneous Electron Transfer
Yang, Jingkui,Felton, Greg A. N.,Bauld, Nathan L.,Krische, Michael J.
, p. 1634 - 1635 (2007/10/03)
The first examples of anion radical cycloaddition induced by homogeneous electron transfer from chemical agents are described. Specifically, upon exposure to chrysene anion radical, bis(enone) substrates are found to engage in stereoselective intramolecular [2 + 2] cycloaddition. These studies, along with the corresponding electrochemically initiated reactions, provide insight into this fundamentally new pattern of reactivity and support the feasibility of expanding this novel reaction type. Copyright
