67233-95-8

Basic information

• Product Name: Benzene, 1-(1-ethoxyethyl)-4-methoxy-
• CAS NO: 67233-95-8
• Molecular Formula: C11H16O2
• Molecular Weight: 180.247
• Mol File: 67233-95-8.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1-ethoxyethyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1-ethoxyethyl)-4-methoxy-(67233-95-8)
• EPA Substance Registry System: Benzene, 1-(1-ethoxyethyl)-4-methoxy-(67233-95-8)

Safety Data

• Hazardous Substances Data: 67233-95-8(Hazardous Substances Data)

Upstream product

• 66821-19-0 1-(1'-ethoxyvinyl)-4-methoxybenzene 
• 637-69-4 4-Methoxystyrene 
• 64-17-5 ethanol 
• 201230-82-2 carbon monoxide 
• 3319-15-1 rac-1-(4-methoxyphenyl)-ethanol 
• 88288-58-8 1-methoxy-4-(1-(1-(4-methoxyphenyl)ethoxy)-ethyl)benzene 
• 1393359-48-2 tert-butyl (2S,3R)-2-[(1S)-1-hydroxyprop-2-en-1-yl]-3-{[(1R)-1-(4-methoxyphenyl)ethyl](methyl)amino}hept-6-enoate 
• 1393359-53-9 tert-butyl (1S,2R,7R)-2-hydroxy-7-{[(1R)-1-(4-methoxyphenyl)ethyl](methyl)amino}cyclohept-3-ene-1-carboxylate 
• 1393359-52-8 tert-butyl (1S,2S,7R)-2-hydroxy-7-{[(1R)-1-(4-methoxyphenyl)ethyl](methyl)amino}cyclohept-3-ene-1-carboxylate 
• 1393359-49-3 tert-butyl (2S,3R)-2-[(1R)-1-hydroxyprop-2-en-1-yl]-3-{[(1R)-1-(4-methoxyphenyl)ethyl](methyl)amino}hept-6-enoate 
• 6298-96-0 1(R)-(4-methoxyphenyl)-ethylamine 
• 1273232-31-7 tert-butyl (2R,3S,4S,5R,αR)-2-hydroxy-3-[N-but-3'-enyl-N-(α-methyl-p-methoxybenzyl)amino]-4,5-O-isopropylidenehept-6-enoate 
• 1258980-78-7 (R)-N-but-3-enyl-N-(α-methyl-p-methoxybenzyl)amine 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Downstream Products

• 4356-69-8 1,1-bis-(4-methoxyphenyl)ethylene 
• 64-17-5 ethanol 
• 94670-31-2 1-(4-methoxyphenyl)ethyl trifluoroethyl ether 
• 3319-15-1 rac-1-(4-methoxyphenyl)-ethanol 

Relevant articles and documents

Chemoenzymatic intermolecular haloether synthesis

A chemoenzymatic method for the synthesis of haloethers is presented. A combination of enzymatic hypohalite synthesis with spontaneous oxidation of alkenes and nucleophilic attack by various alcohols enabled the synthesis of a wide range of haloethers. The reaction system has been characterised and current imitations have been worked out. In the present, aqueous reaction system, hydroxyhalide formation represents the main undesired side reaction. Nevertheless, semi-preparative scale synthesis of a range of haloethers is demonstrated.

Direct synthesis of ethers from aldehydes and ketones. One-pot reductive etherification of benzaldehydes, alkyl aryl ketones, and benzophenones

Benzyl alcohols formed by the reduction of benzaldehydes, alkyl aryl ketones, and benzophenones with sodium tetrahydridoborate in alcohols undergo in situ etherification with the solvent in the presence of a catalytic amount of HCl. Thus the process may be regarded as one-pot transformation of carbonyl compounds into the corresponding benzyl ethers. The yields of ethers depend on the substituent nature in the aromatic fragment of the initial carbonyl compound and on the alcohol used as reduction medium.

Selective catalytic synthesis of unsymmetrical ethers from the dehydrative etherification of two different alcohols

The cationic ruthenium-hydride complex [(C6H6)(PCy3)(CO)RuH]+BF4- catalyzes selective etherification of two different alcohols to form unsymmetrically substituted ethers. The catalytic method exhibits a broad substrate scope while tolerating a range of heteroatom functional groups in forming unsymmetrical ethers, and it is successfully used to directly synthesize a number of highly functionalized chiral nonracemic ethers.