67236-72-0Relevant academic research and scientific papers
Asymmetric phase-transfer catalytic sulfanylation of some 2-methylsulfinyl cyclanones. Modeling of the stereochemical course of the aldol reaction of (SS,2S)-2-methylsulfinyl-2-methylsulfanylcyclohexanone
Rodrigues, Alessandro,Wladislaw, Blanka,Vitta, Claudio Di,Filho, José Eduardo Pandini Cardoso,Marzorati, Liliana,Bueno, Mauro Alves,Olivato, Paulo Roberto
, p. 5344 - 5348 (2010)
Increased diastereoisomeric excesses are obtained for the sulfanylation reactions of some 2-methylsulfinyl cyclanones under phase-transfer catalysis using the chiral catalyst QUIBEC instead of TEBA. The optically pure (SS,2S)-2-methylsulfinyl-2-methylsulf
Phase transfer catalysis (PTC) sulfanylation of some 2-methylsulfinyl- cyclanones
Wladislaw, Blanka,Bueno, Mauro Alves,Marzorati, Liliana,Di Vitta, Claudio,Zukerman-Schpector, Julio
, p. 9296 - 9298 (2007/10/03)
The sulfanylation reactions of 2-methylsulfinylated cyclopentanone, 1-indanone, and cyclohexanone by a PTC procedure are reported and the yields and diastereoselectivity compared to those obtained by the homogeneous-phase method. The stability of the sulf
