67254-06-2

Upstream product

• 629-05-0 n-octyne 
• 876621-18-0 trans-[Pt(C₆H₄Me-p)(SC₆H₄OCH₃-p)(PPh₃)2] 
• 455-13-0 4-Iodobenzotrifluoride 
• 624-31-7 4-tolyl iodide 

Downstream Products

• 174967-10-3 trans-Pt(C_.tplbond.ruthenocenyl)(PPh₃)2C₆H₄Me-p 
• 166987-32-2 Pt((C₂C₅H₄)Fe(C₅H₅))(P(C₆H₅)3)2(C₆H₄CH₃) 
• 72022-41-4 1-(4-methylphenyl)-2-ferrocenylacetylene 
• 1542226-80-1 trans-Pt{C≡CC6H4N(C6H4CH3-4)2}(C6H4CH3-4)(PPh3)2 

Relevant academic research and scientific papers

Platinum-catalyzed reaction of alkynes with ArI (Ar = aryl and thienyl) and Ar′SM (M = Na, K, and Sn(Bu-n)3): Three- vs two-component cross-coupling reaction

The Pt-catalyzed reactions of terminal alkynes HCCR (2) with ArI (6) (Ar = aryl and thienyl) and Ar′SM (M = Li, Na, K, and Sn(n-Bu3)) (7) have been examined. Among them, the combined use of 2- and 3-iodothiophene with PhSK resulted in the formation of (Z)-Ar(H)C=C(SAr′)(R) (5) in moderate to good yields. When aryl iodide was employed as a coupling partner, thioether ArSAr′ (4), a direct cross-coupling product between 6 and 7, was competitively produced together with 5. The ratios of formation of 5/4 were significantly dependent on the substituent in Ar of 6 and Ar′ of 7 as well as species of 2. The mechanistic study indicated that 4 was produced by the alkyne-participated reaction of 6 with Pt(Ar)(SAr′)(PPh3) 2 (1).