67281-97-4

Basic information

• Product Name: 2,2,2-trichloroethyl 6α-benzyloxypenicillanate
• Synonyms: 2,2,2-trichloroethyl 6α-benzyloxypenicillanate
• CAS NO: 67281-97-4
• Molecular Weight: 438.759
• Mol File: 67281-97-4.mol

Chemical Properties

• CAS DataBase Reference: 2,2,2-trichloroethyl 6α-benzyloxypenicillanate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trichloroethyl 6α-benzyloxypenicillanate(67281-97-4)
• EPA Substance Registry System: 2,2,2-trichloroethyl 6α-benzyloxypenicillanate(67281-97-4)

Safety Data

• Hazardous Substances Data: 67281-97-4(Hazardous Substances Data)

Upstream product

• 26774-86-7 2,2,2-trichloroethyl 6β-phenylacetamidopenicillanate 
• 51056-23-6 6β-(nitroso-phenylacetyl-amino)-penicillanic acid 2,2,2-trichloro-ethyl ester 
• 51056-24-7 (2S,5R)-6-Diazo-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 2,2,2-trichloro-ethyl ester 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Preparation of 6α-Monosubstituted and 6,6-Disubstituted Penicillanates from 6-Diazopenicillanates: Reactions of 6-Diazopenicillanates with Alcohols, Thiols, Phenylseleninyl Compounds, and Allylic Sulphides, and their Analogues

Reactions of 6-diazapenicillanates (1) and (2) with a range of compounds, in some cases catalysed by BF3-Et2O or Cu(acac)2, have been investigated, and found to be useful for the synthesis of 6α-monosubstituted and 6,6-disubstituted penicillanates.Thus th