67306-03-0

Basic information

• Product Name: FENPROPIMORPH
• Synonyms: MILDOFIX;MISTRAL;MISTRAL T;4-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)-2,6-dimethyl-morpholin;4-(3-(4-(1,1-Dimethylethyl)phenyl)-2-methylpropyl)-2,6-dimethylmorpholine;4-[3-(4-tert-Butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine;BAS 421F;bas42100f
• CAS NO: 67306-03-0
• Molecular Formula: C₂₀H₃₃NO
• Molecular Weight: 303.48
• EINECS: 266-719-9
• Mol File: 67306-03-0.mol
• Article Data: 6

Chemical Properties

• Melting Point: 25°C
• Boiling Point: bp0.05 120°
• Flash Point: 115.6 °C
• Appearance: /
• Density: 0.9804 (rough estimate)
• Vapor Pressure: 2.25E-06mmHg at 25°C
• Refractive Index: 1.5614 (estimate)
• Storage Temp.: 0-6°C
• Water Solubility: 4.3mg/L(temperature not stated)
• CAS DataBase Reference: FENPROPIMORPH(CAS DataBase Reference)
• NIST Chemistry Reference: FENPROPIMORPH(67306-03-0)
• EPA Substance Registry System: FENPROPIMORPH(67306-03-0)

Safety Data

• RIDADR: 2902
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 67306-03-0(Hazardous Substances Data)

Usage

Definition

ChEBI: A member of the class of morpholines that is 2,6-dimethylmorpholine in which the hydrogen attached to the nitrogen is replaced by a 3-(p-tert-butylphenyl)-2-methylpropyl group.

InChI:InChI=1/C20H33NO/c1-15(12-21-13-16(2)22-17(3)14-21)11-18-7-9-19(10-8-18)20(4,5)6/h7-10,15-17H,11-14H2,1-6H3/t15?,16-,17+

Upstream product

• 141-91-3 2,6-dimethyl morpholine 
• 80-54-6 lilial 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 13586-68-0 p-tert-butyl-α-methyl-3-phenylprop-2-enal 
• 67305-99-1 4-[3-(4-tert-butyl-phenyl)-2-methyl-propenyl]-2,6-dimethyl-morpholine 

Downstream Products

• 67306-61-0 4-[3-(4-tert-butyl-phenyl)-2-methyl-propyl]-2,6-dimethyl-morpholine 4-oxide 

Relevant articles and documents

Pd-catalysed β-selective C(sp3)-H arylation of simple amides

An efficient Pd-catalysed β-C(sp3)-H arylation of diverse native amides with aryl iodides was developed. This protocol overcomes the necessity of the Thorpe-Ingold effect and features broad substrate scope and good functional group tolerance. The potential application of this protocol is collectively demonstrated by gram-scale synthesis and the synthesis of several bioactive molecules.

P-hydroxyaniline derivatives, their preparation and their use

p-Hydroxyaniline derivatives of the formula I STR1 where the substituents have the following meanings: R1 is unsubstituted or substituted bicycloalkyl or bicycloalkenyl; R2 and R3 independently of one another are halogen, alkyl, haloalkyl, alkoxy or haloalkoxy; R4 is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl or aryl, OR5 or NR5 R6, where R5 is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl or aryl, and R6 is hydrogen or alkyl, and their salts, processes for their preparation, compositions containing them and their use for controlling harmful fungi or pests are described.

Process for the preparation of morpholine and piperidine derivatives

The invention relates to an improved process for the preparation of fungicidally active compounds of the formula STR1 wherein R1 and R2 individually are lower alkyl of from 1 to 4 carbons or halo-(lower alkyl) of from 1 to 4 carbons or R1 and R2 together with the carbon to which they are attached form a 3 to 7 membered cycloalkyl ring or lower alkyl-substituted cycloalkyl of from 4 to 9 carbons, R3, R4 and R5 individually are hydrogen or lower alkyl of from 1 to 4 carbons and X is methylene or oxygen, and salts of those compounds which are basic. The improved process comprises the reaction of a compound of the formula, STR2 wherein R3, R4, R5 and X have the significance given hereinabove, with a compound which forms a carbonium ion of the formula STR3 wherein R1 and R2 have the significance as given hereinabove.