67347-53-9Relevant academic research and scientific papers
The Stabilities of Meisenheimer Complexes. Part 42. Kinetic Studies of the Reactions of Methyl 3,5-Dinitrobenzoate and of Methyl 4-Chloro-3,5-dinitrobenzoate with Hydroxide ions in Dimethyl Sulphoxide-Water Mixtures. Competitive Nucleophilic Attack at Aryl and Carbonyl Carbon Atoms
Crampton, Michael R.,Greenhalgh, Colin
, p. 873 - 878 (1986)
Kinetic and equilibrium data, obtained by stopped-flow spectrophotometry, are reported for the reactions of methyl 3,5-dinitrobenzoate (1) and methyl 4-chloro-3,5-dinitrobenzoate (5) with hydroxide ions in dimethyl sulphoxide-water mixtures.There is evidence for competition between attack at carbonyl and aryl carbon atoms, the latter becoming relatively favoured as the proportion of dimethyl sulphoxide in the solvent is increased.It is shown that the major pathway in the formation of 4-hydroxy-3,5-dinitrobenzoate from (5) involves hydroxide attack at the carbonyl function followed by slow attack at the ring carbon atom carrying chlorine.
Salt Effects on Supramolecular Complexation and Catalysis
Schneider, Hans-Joerg,Theis, Isolde
, p. 3066 - 3070 (2007/10/02)
Complexation equilibria between a positively charged azoniacyclophane (CP66) and naphthalene-2-carboxylate in water show a linear Debye-Hueckel correlation with a sensitivity of m = -1.5 compared to the m = -4.1 for pure ionic complexes observed experimen
