67425-61-0Relevant academic research and scientific papers
Syntheses and Thermal Behaviour of Compounds of the Type cis-(Phenyl)(phenyl')bis(triphenylphosphane)platinum(II) with Substituents of Different Character in the Platinum-bound Phenyl Rings
Brune, Hans-Albert,Hess, Reiner,Schmidtberg, Guenther
, p. 1772 - 1780 (2007/10/02)
16 compounds of the types cis- (cis-6a-g) and cis- (cis-7a-g) (Ar = Phenyl ring substituted by at least one electron acceptor or donator substituent) have been synthesized and studied with respect to the thermal reductive elimination of the biphenyl system. - Keywords: Bis(phenyl)platinum Compounds, Syntheses, Thermal Elimination
Aryl(halogeno)bis(triphenylphosphane)platinum(II) Compounds. Syntheses and cis-trans Isomerizations
Ertl, Josef,Grafl, Dieter,Brune, Hans Albert
, p. 1082 - 1090 (2007/10/02)
The syntheses of the platinum-organic compounds cis- (X = H, 3-H3C-, 3-H3CO-, 4-H3C-, 4-H3CO-) and cis- (X = H, 3-H3C-, 3-H3CO-, 3-(H3C)2N-, 4-H3C-, 4-H3CO-) are described; their thermal isomerization in crystalline phase are studied and the resulting trans-isomers characterized. - Key words: Platinum(II) Complexes, Syntheses, Isomerizations
