67431-04-3Relevant academic research and scientific papers
Ortho-Acidic aromatic thiols as efficient catalysts of intramolecular Morita-Baylis-Hillman and Rauhut-Currier reactions
Selig, Philipp S.,Miller, Scott J.
supporting information; experimental part, p. 2148 - 2151 (2011/05/05)
ortho-Mercaptobenzoic acid and ortho-mercaptophenols were discovered as efficient thiol catalysts of both the intramolecular Morita-Baylis-Hillman (MBH) and Rauhut-Currier (RC) reaction. High reaction rates were achieved under mildly basic, aqueous condit
Enantioselective catalysis of intramolecular Morita-Baylis-Hillman and related reactions by chiral rhenium-containing phosphines of the formula (η5-C5H5)Re(NO)(PPh3)(CH 2PAr2)
Seidel, Florian,Gladysz, John A.
, p. 986 - 988 (2008/02/03)
The racemic rhenium-containing phosphine (η5-C 5H5)Re(NO)(PPh3)(CH2PPh 2) catalyzes intramolecular Morita-Baylis-Hillman reactions of four R(CO)CH=CH(CH2)nCH2/su
Reductive Cleavage of 4,5-Cycloalkanoisoxazolines
Lakhvich, F. A.,Khripach, V. A.,Pyrko, A. N.,Antonevich, I. P.,Yankova, T. V.,et al.
, p. 800 - 804 (2007/10/02)
Different variants of the reductive cleavage of 4,5-cycloalkanoisoxazolines under the influence of Raney nickel in the presence of acids were studied.The compositions, structures, and properties of the reaction products are discussed.
LA REACTION DE WITTIG-HORNER EN MILIEU HETEROGENE IX. BIS ALDOLISATION DES PHOSPHONATES A PARTIR DES DIALDEHYDES ALIPHATIQUES EN MILIEU AQUEUX PEU BASIQUE. SYNTHESE DE CYCLENOLS FONCTIONNELS.
Graff, M.,Dilaimi, A. Al,Seguineau, P.,Rambaud, M.,Villieras, J.
, p. 1577 - 1578 (2007/10/02)
Aqueous solutions of glutaraldehyde and succinaldehyde give respectively improved yields of 1-functional 6-cyclohexenols and 5-cyclopentenols, when subjected to WITTIG-HORNER reaction in water at room temperature, with potassium carbonate as a base.
