67438-13-5Relevant academic research and scientific papers
Bifunctional Reactivity of the Nitrophenoxyl Group in Intramolecular Photoreactions
Mutai, Kiyoshi,Tukada, Hideyuki,Nakagaki, Ryoichi
, p. 4896 - 4903 (2007/10/02)
The photochemical behavior of a homologous series of compounds, p-O2NC6H4O(CH2)nNHPh (n = 2-10, 12, and 16) in acetonitrile is reported.The lower (n = 2-6) homologues undergo an apparently nucleophilic type rearrangement to give ω-((p-nitrophenyl)amino)al
Photoinduced Intramolecular Aromatic Nucleophilic Substitution (the Photo-Smiles Rearrangement) in Amino Ethers
Mutai, Kiyoshi,Kobayashi, Keiji
, p. 462 - 465 (2007/10/02)
Intramolecular rearrangement was induced by light as well as base in a homologous series of 1-(p-nitrophenoxy)-ω-anilinoalkanes, p-O2NC6H4O(CH2)nNHPh(n=2-5), yielding N-(p-nitrophenyl)-ω-anilino-1-alkanols, p-O2NC6H4N(Ph)(CH2)nOH.The reaction rate in acet
