67456-43-3Relevant academic research and scientific papers
HYDROBORATION D'AMINES INSATUREES. V. NOUVELLE VOIE D'ACCES AUX AMIOALKYLIDENECYCLOALKANES
Torregrosa, Jean-Luc,Baboulene, Michel,Speziale, Vincent,Lattes, Armand
, p. 311 - 318 (2007/10/02)
Hydroboration of various 1-bromopropargylamines by borinane and 3,6-dimethylborepane has led to α-bromovinylboranes.Treatment of these compounds with iodine in basic media, only gives aminoalkylidenecycloalkanes with excellent yields.
REGIO- AND STEREOSPECIFIC SYNTHESIS OF ALLYLIC TERTIARY AMINES
Cavalla, David,Warren, Stuart
, p. 4505 - 4508 (2007/10/02)
E and Z allylic amines have been synthesised by stereospecific elimination of Ph2PO2- from pure diastereoisomers (3) and (4).
