674780-19-9Relevant academic research and scientific papers
Novel peripherally functionalized seco-porphyrazines: Synthesis, characterization and spectroscopic evaluation
Sakellariou, Efstathia G.,Montalban, Antonio Garrido,Beall, Scott L.,Henderson, David,Meunier, Hubert G.,Phillips, David,Suhling, Klaus,Barrett, Anthony G. M.,Hoffman, Brian M.
, p. 9083 - 9090 (2003)
Co-macrocyclizations of 2,3-dipropylmaleonitrile and 2,3-di-(4- (methoxycarbonyl)phenyl)maleonitrile, respectively, with N,N′-dibenzyl-N, N′-di-(11-tetrahydropyranyloxy-3,6,9-trioxo-undecyl))maleonitrile and N,N,N′,N′-tetramethylmaleonitrile were used to prepare derivatives of the 4,5-diamino-porphyrazine systems including the zinc(II) complexes. Subsequent oxidation of the macrocycles with potassium permanganate gave the corresponding seco-porphyrazines. These were shown to be efficient sensitizers for the production of singlet oxygen (ΦΔ=0.15-0.57) by the determination of their photophysical properties.
THE PREPARATION OF A DYE COMPOUND AND A METHOD FOR MAKING THE SAME
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Page/Page column 12, (2010/12/26)
The invention relates to a dye compound consisting of four cyclically linked components, the four components comprising at least one linker compound. According to the invention the at least one linker compound is selected from a first linker compound or a second linker compound, the first linker compound having an aromatic carboxylic acid or an alkyl ester thereof, the aromatic group being bonded to fumaronitrile, and the second linker compound having an aromatic carboxylic acid or an alkyl ester thereof, the aromatic group being bonded to phthalonitrile.
