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CAS

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674800-06-7

[IrCl2(NH2Ph)(η-C5Me5)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 674800-06-7 Structure

  • Basic information

    1. Product Name: [IrCl2(NH2Ph)(η-C5Me5)]
    2. Synonyms:
    3. CAS NO:674800-06-7
    4. Molecular Formula:
    5. Molecular Weight: 491.483
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 674800-06-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [IrCl2(NH2Ph)(η-C5Me5)](CAS DataBase Reference)
    10. NIST Chemistry Reference: [IrCl2(NH2Ph)(η-C5Me5)](674800-06-7)
    11. EPA Substance Registry System: [IrCl2(NH2Ph)(η-C5Me5)](674800-06-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 674800-06-7(Hazardous Substances Data)

674800-06-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 674800-06-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,7,4,8,0 and 0 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 674800-06:
(8*6)+(7*7)+(6*4)+(5*8)+(4*0)+(3*0)+(2*0)+(1*6)=167
167 % 10 = 7
So 674800-06-7 is a valid CAS Registry Number.

674800-06-7Downstream Products

674800-06-7Relevant articles and documents

Room-temperature cyclometallation of amines, imines and oxazolines with [MCl2Cp*]2 (M = Rh, Ir) and [RuCl2(p-cymene)]2

Davies, David L.,Al-Duaij, Omar,Fawcett, John,Giardiello, Marco,Hilton, Stephen T.,Russell, David R.

, p. 4132 - 4138 (2003)

N,N-Dimethylbenzylamine, alkyl and aryl imines derived from benzaldehyde, and 2-phenyl-4,4-dimethyloxazoline all undergo cyclometallation with [IrCl2Cp*]2 (Cp* = η-C5Me5) when treated with NaOAc in dichloromethane at room temperature. The imines are also cyclometallated by [RhCl2Cp*]2 under the same conditions whilst only N-alkyl imines are cyclometallated by [RuCl2(p-cymene)]2. The role of acetate in the cyclometallation is more than just as a base. X-Ray structures of cyclometallated complexes [MCl{C6H4-2-C(H)=NCH2CH2OMe-κC ,N}(η-ring)] (M = Ir, Rh ring = Cp* M = Ru, ring = p-cymene), [MCl{C6H4-2-C(H)=NCH2CH2OMe-κC ,N}Cp*](M = Ir, Rh). [RuCl(η2-O2CMe)(p-cymene)] and [IrCl2(NH2Ph)Cp*] are reported.

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