675107-55-8Relevant articles and documents
Conversion of phenols into selenophenols: Seleno newman-kwart rearrangement
Sorensen, Anne,Rasmussen, Brian,Agarwal, Shubham,Schau-Magnussen, Magnus,Solling, Theis I.,Pittelkow, Michael
, p. 12346 - 12349 (2013)
A 'Se'lling point: The first thermally induced OAr→Se Ar migration reaction is reported, and it can be used to prepare aryl selenols in three steps from the corresponding phenols. O-aryl selenocarbamates rearrange to Se-aryl carbamates via a four-membered transition state (see scheme). The aryl selenols (isolated as the diselenides) can be prepared by hydrolysis of the Se-aryl selenocarbamates. Copyright
Palladium-catalyzed insertion reactions of isocyanides into thiocarbamates and selenocarbamates
Shiro, Daisuke,Fujiwara, Shin-Ichi,Tsuda, Susumu,Iwasaki, Takanori,Kuniyasu, Hitoshi,Kambe, Nobuaki
supporting information, p. 465 - 467 (2015/05/20)
The insertion reaction of isocyanides with thiocarbamates and selenocarbamates in the presence of a Pd(0) catalyst to selectively give 2-oxoethanimidothioates and -selenoates is reported. This is the first example of the insertion of an isocyanide into a
Palladium-catalyzed intramolecular selenocarbamoylation of alkynes with carbamoselenoates: Formation of α-alkylidene-β-lactam framework
Toyofuku, Masashi,Fujiwara, Shin-Ich,Shin-Ike, Tsutomu,Kuniyasu, Hitoshi,Kambe, Nobuaki
, p. 9706 - 9707 (2007/10/03)
Pd-catalyzed intramolecular selenocarbamoylation of alkynes leading to α-alkylidene-β-lactams was developed. This reaction can be applied to thiocarbamoylation and to the synthesis of δ- and ε-lactams and a cyclobutanone. Copyright
