67517-34-4

Upstream product

• 67517-33-3 [5-((2E,6E)-8-Hydroxy-3,7-dimethyl-octa-2,6-dienyl)-2,6,6-trimethyl-cyclohex-1-enyl]-acetonitrile 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 26187-80-4 2,6-trans-2,6-dimethyl-8-hydroxy-2,6-octadienoic acid 
• 67517-30-0 (2E,6E)-8-(3-Cyanomethyl-2,2,4-trimethyl-cyclohex-3-enyl)-2,6-dimethyl-octa-2,6-dienoic acid methyl ester 
• 40772-83-6 2,6-trans-2,6-dimethyl-8-hydroxy-2,6-octadienoic acid methyl ester 
• 21677-96-3 geranyl cyanide 
• 67537-00-2 (2E,6E)-8-((3S,4R)-4-Chloro-3-cyanomethyl-2,2,4-trimethyl-cyclohexyl)-2,6-dimethyl-octa-2,6-dienoic acid methyl ester 
• 67517-29-7 (2E,6E,12E)-9-(1-Chloro-1-methyl-ethyl)-14-cyano-2,6,12-trimethyl-tetradeca-2,6,12-trienoic acid methyl ester 
• 67517-28-6 methyl (2E,6E)-8-chloro-2,6-dimethyl-2,6-octadienoate 

Relevant academic research and scientific papers

Synthesis of 10-cyanoverticillene and its reactions directed toward the verticillol synthesis

Directed toward the synthesis of verticillols, 10-cyanoverticillene 8 was settled as a key intermediate. Bond formation of cyano chloride 7 possessing secoverticillane skeleton to the key intermediate 8 with LiN(TMS)2 at 60°C proceeded smoothly