67535-54-0Relevant academic research and scientific papers
Effect of Bulky Size of Carbonyl Systems on Betaine Decomposition of Semi-stablized Arsonium Ylids
Gupta, K. C.,Srivastava, N.,Nigam, R. K.
, p. 802 - 803 (2007/10/02)
Reactions of substituted benzylidentriphenylarsenanes (2a-i) with 9-anthraldehyde and 9-fluorenone have been studied using benzene-sodamide, chloroform-sodium hydride and methanol-sodium ethoxide as solvent-base pairs.In all the cases olefins (5a-i and 6a-i) are formed exclusively.Variation of solvents and bases has no effect on the course of betaine decomposition formed by the nucleophilic attack of ylids on carbonyl systems.
